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공공누리This item is licensed Korea Open Government License

Title
Anion-dependent interpenetration in lattices of Ag(I) complexes of a divergent quaterpyridine-donor ligand
Author(s)
신종원김양Jack HarrowfieldShinya Hayami이영훈
Publication Year
2017-07-07
Abstract
Crystal structure determinations for the divergent quaterpyridine-type ligand bis-1,4-(di-4-pyridylaminomethyl)benzene, dpab, and its complexes with silver(I)trifluoroacetate and nitrate have revealed the operation of different weak interactionswithin the lattices. Coordination of four pyridyl-N donors to Ag(I) in the trifluoroacetateresults in a 3-dimensional coordination polymer with the uncoordinated anions heldwithin the cavities created by that polymer. In the nitrate, only two pyridyl-N donors arebound to each of the two inequivalent Ag(I) centres and the lattice contains twointerpenetrating coordination polymers linked by CH…O interactions involving thecoordinated anions.
Keyword
 silver coordination polymers; chemical interactions
Journal Title
polyhedron
Citation Volume
130
ISSN
0277-5387
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Appears in Collections:
7. KISTI 연구성과 > 학술지 발표논문
URI
https://repository.kisti.re.kr/handle/10580/14649
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