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공공누리This item is licensed Korea Open Government License

Title
Lattice interactions of terpyridines and their derivatives-free terpyridines and their protonated forms
Author(s)
이영훈김양Jack HarrowfieldShinya Hayami Artur R. Stefankiewicz김지영신종원
Publication Year
2016-11-07
Abstract
Consideration of the crystal structures of four new 2,2′;6′,2″-terpyridine derivatives in terms of the weaklattice interactions which can be discerned through calculation of their Hirshfeld surfaces shows that despitethe common feature of stacking of the near-planar aromatic entities, specific interactions beyond dispersionwithin the stacked arrays are relatively uncommon. This is in accord with what is seen in the sameanalysis of the structures of known analogues, which provides context for the present work. That this is notsimply a consequence of the transoid array of the N-donors in these free ligands is seen from extension ofthe Hirshfeld surface analysis to the structures of protonated species where cisoid arrays are seen
Keyword
Terpyridine; protonated form
Journal Title
CrystEngComm
Citation Volume
18
ISSN
1466-8033
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Appears in Collections:
7. KISTI 연구성과 > 학술지 발표논문
URI
https://repository.kisti.re.kr/handle/10580/14540
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