KISTI repository
BROWSE
download0
view670
This item is licensed Korea Open Government License
- Alternative Title
- Ti-V-O 산화물의 상변화에서 하소분위기및 온도의 영향
- Publication Year
- 2011-12-30
- Abstract
- Ti1-xVxO2 oxides were produced by a coprecipitation process using TiCl4 and VOCl3 as starting materials. As-precipitated gels were calcined at 500~800°C, either in a vacuum or oxygen atmosphere. Effects of the calcination atmosphere and temperature on the phase transition of crystalline Ti-V-O oxides were studied. Calcination in an oxygen atmosphere produced Ti-V-O oxides, which are mixtures of TiO2 and V2O5 oxides formed for all the calcination temperatures. Calcinations at 800°C in vacuum resulted in the formation of a rutile Ti1-xVxO2 single phase for all compositions of vanadium. A significant portion of vanadium ions is incorporated into the TiO2 lattice, which consistently decreases the lattice parameters of the rutile Ti1-xVxO2 phase as the vanadium addition increases.
- Keyword
- vanadium-doped titania; coprecipitation; anatase; rutile; calcination
- Journal Title
- Electronic materials letters
- Citation Volume
- 7
- ISSN
- 1738-8090
- Files in This Item:
- There are no files associated with this item.
- Appears in Collections:
- 7. KISTI 연구성과 > 학술지 발표논문
