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공공누리This item is licensed Korea Open Government License

Title
synthesis and characterization of triphenylamine derivatives by oxidative polymerization
Author(s)
심재호이상호
Publication Year
2008-11-28
Abstract
Hole transport polymers consisting of P-MOTPA and P-BTPA were synthesized by oxidative coupling reaction using FeCl3 as an oxidant. These polymers had good solubility and their thin films showed sufficient morphological stability. H-NMR and C-NMR revealed that the monomers were exclusively connected at the para positions of unsubstituted phenyl groups. Polymers had UV absorption maximum around 370 nm. Cyclic voltammograms of polymers showed well-defined pairs of reduction and oxidation peaks at 1.1 V versus Ag/AgCl, indicating that the polymers are electrochemically active. P-MOTPA and P-BTPA had hole drift mobility.
Keyword
oxidative polymerization; reduction; oxidation; triphenylamine
Journal Title
Synthetic metals
Citation Volume
157
ISSN
0379-6779
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Appears in Collections:
7. KISTI 연구성과 > 학술지 발표논문
URI
https://repository.kisti.re.kr/handle/10580/13707
http://www.ndsl.kr/ndsl/search/detail/article/articleSearchResultDetail.do?cn=NART37302960
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